O-Ring Materials - VITON™, FPM, FKM, HK
Viton™ Fluoroelastomer (FKM / FPM) Seals Engineering Properties & Industrial Applications
Fluoroelastomer (a highly cross-linked synthetic rubber polymer classified under international terminology standards as FKM by ASTM, FPM by ISO, and designated as HK class material within ASTM D2000, commonly recognized via the prominent brand name Viton™) represents a premium tier of synthetic elastomer containing fluorine atoms on the carbon backbone or side chains of its molecular matrix.
The extreme electronegativity of fluorine atoms combined with the powerful fluorine-carbon bond energy (F-C bond) unlocks world-class thermal stability, elite chemical inertness, top-tier resistance to petroleum fluids and organic solvents, and an incredibly low outgassing rate in high-vacuum configurations. Consequently, it has become the baseline standard sealing component utilized in semiconductor lithography chambers, heavy chemical processing plants, aerospace propulsion, and high-precision automotive fuel delivery networks.
CNL SEALS maintains an extensive live warehouse of tens of thousands of standard Viton™ FKM O-ring specifications (fully compliant with AS568 and JIS B2401) alongside advanced custom precision tooling molding services.
Viton™ FKM Elastomer Core Technical Specifications
Operating Temperature Window: Continuous -20℃ ~ +200℃ .
Durometer/Hardness Scale: 50 to 90 Shore A (Standard catalog variants are maintained at 70 Shore A and 90 Shore A, adaptable to specific design criteria).
Specification Compliance Matrix: Fully integrated with ASTM D2000 and SAE J200 classification parameters.
Regulatory & Environmental Mandates: 100% compliant with SGS-verified RoHS, REACH, and Halogen-Free industrial standards.
Key Engineering Advantages & Media Compatibility
Exceptional Thermal & Oxidative Longevity: Retains supreme sealing elasticity and anti-aging memory under continuous exposure to 200℃ atmospheric heat, displaying flawless resistance to ozone cracking and solar UV aging.
Top-Tier Fuel & Solvent Shield: Exhibits extremely minimal swelling and pristine property retention when operating in petroleum-based lubricants, hydraulic oils, motor fuels, diesel, vegetable grease, and aggressive aromatic/chlorinated hydrocarbons (such as toluene or trichloroethylene).
Supreme Corrosion Resistance: Effectively repels degradation when interfacing with most volatile inorganic mineral acids (such as diluted sulfuric and hydrochloric acids), sodium hydroxide alkalis, industrial bleaching chemicals, and highly reactive chemical media.
High-Vacuum Sealing Efficiency: Features a dense molecular matrix that delivers an exceptionally minimal outgassing rate within ultra-high vacuum chambers, preventing process contamination.
Material Constraints & Unsupported Working Environments
Vulnerable to Highly Polar Media: FKM compounds are strictly not recommended for exposure to low molecular weight organic acids, volatile ketones (such as acetone, MEK), esters (e.g., ethyl acetate), and nitro compounds, which trigger rapid volumetric swelling and mechanical breakdown. (For total universal chemical resistance, upgrading to FFKM perfluoroelastomer is advised).
Vulnerable to High-Pressure Steam: Conventional bisphenol-cured FKM is prone to hydrolytic cleavage in ultra-high temperature water steam environments. For heavy steam routing, specialized peroxide-cured FKM variants or EPDM compounds must be deployed.
Primary Industrial Application Scopes
Semiconductor & Optoelectronics Manufacturing: Vacuum chamber door gaskets, Chemical Vapor Deposition (CVD) sub-system gas lines, and high-purity thermal-chemical resistant O-rings.
Chemical Processing & Heavy Industrial Pumps: Aggressive chemical media transfer pump seals, chemical-resistant fluid valve seats, and high-temperature autoclave gaskets.
Automotive Drivetrain & Aerospace Propulsion: High-pressure fuel injection manifold O-rings, high-RPM crankshaft thermal oil seals, engine valve stem seals, and high-temperature military aviation hydraulic line seals.
Best● Better○ Good△ BadX
| Rubber type (ASTM Abbreviation ) | Fluoro Carbon Rubber VITON™, FPM, FKM, HK | ||
| Chemical structure | Hexafluoropropylene fluoroethylene copolymer | ||
| Main feature | Heat-resistant, oil-resistant, chemical-resistant, solvent-resistant; not resistant to ketones, esters and nitrate-containing mixtures. | ||
| Pure rubber properties | proportion Muni viscosity ML1+ (100℃) | 1.80 ∼ 1.82 65 ∼ 180 | |
| Physical properties of synthetic rubber | Possible JIS hardness range General temperature range(℃) Special temperature range(℃) Tensile strength (kg/cm2) Elongation (%) Anti-elastic Cracking Wear resistance Bending resistance | 50 ∼ 90 -20 ∼ 200 -30 ∼ 275 70 ∼ 200 500 ∼ 100 △ ○ ● ○ | |
| Various properties of synthetic rubber | lubricating oil | Engine oil Gear Oil Motor oil Shaft lubricant Refrigeration oil Butter Lithium oil Oyster sauce | ● ● ● ● ● ● ● ● |
| Working oil | Pot shaft oil Oil + Water emulsion system Water + Glycol Phosphate ester Si Brake Fluid Gear oil | ● ○ ○ ● ● △ ● | |
| Fuel oil | Light oil、kerosene Heavy oil Gasoline | ● ● ● | |
| Water | Water、Warm water Water vapor、Hot water Antifreeze water Water cutting oil | ○ △ ○ ○ | |
| Drug | Hydrochloric acid 20% | ● ● ● X △ △ ○ ● ○ ● X ~ △ X X | |
| Gas | LPG Urban gas Ozone Freon 12 Freon 22 | ● ● ● ● △ | |
| Other | Food Sanitation Law | ● ● | |
| The main purpose | O ring, diaphragm, box lining, hose, rocket missile, pump parts, etc. Seals for steam, locomotives, diesel engines, and the semiconductor industry. | ||