O-Ring Materials - VITON™, FPM, FKM, HK

O-Ring Materials - VITON™, FPM, FKM, HK

Viton™ Fluoroelastomer (FKM / FPM) Seals Engineering Properties & Industrial Applications

Fluoroelastomer (a highly cross-linked synthetic rubber polymer classified under international terminology standards as FKM by ASTM, FPM by ISO, and designated as HK class material within ASTM D2000, commonly recognized via the prominent brand name Viton™) represents a premium tier of synthetic elastomer containing fluorine atoms on the carbon backbone or side chains of its molecular matrix.

The extreme electronegativity of fluorine atoms combined with the powerful fluorine-carbon bond energy (F-C bond) unlocks world-class thermal stability, elite chemical inertness, top-tier resistance to petroleum fluids and organic solvents, and an incredibly low outgassing rate in high-vacuum configurations. Consequently, it has become the baseline standard sealing component utilized in semiconductor lithography chambers, heavy chemical processing plants, aerospace propulsion, and high-precision automotive fuel delivery networks.

CNL SEALS maintains an extensive live warehouse of tens of thousands of standard Viton™ FKM O-ring specifications (fully compliant with AS568 and JIS B2401) alongside advanced custom precision tooling molding services.

Viton™ FKM Elastomer Core Technical Specifications

  • Operating Temperature Window: Continuous -20℃ ~ +200℃ .

  • Durometer/Hardness Scale: 50 to 90 Shore A (Standard catalog variants are maintained at 70 Shore A and 90 Shore A, adaptable to specific design criteria).

  • Specification Compliance Matrix: Fully integrated with ASTM D2000 and SAE J200 classification parameters.

  • Regulatory & Environmental Mandates: 100% compliant with SGS-verified RoHS, REACH, and Halogen-Free industrial standards.

Key Engineering Advantages & Media Compatibility

  • Exceptional Thermal & Oxidative Longevity: Retains supreme sealing elasticity and anti-aging memory under continuous exposure to 200℃ atmospheric heat, displaying flawless resistance to ozone cracking and solar UV aging.

  • Top-Tier Fuel & Solvent Shield: Exhibits extremely minimal swelling and pristine property retention when operating in petroleum-based lubricants, hydraulic oils, motor fuels, diesel, vegetable grease, and aggressive aromatic/chlorinated hydrocarbons (such as toluene or trichloroethylene).

  • Supreme Corrosion Resistance: Effectively repels degradation when interfacing with most volatile inorganic mineral acids (such as diluted sulfuric and hydrochloric acids), sodium hydroxide alkalis, industrial bleaching chemicals, and highly reactive chemical media.

  • High-Vacuum Sealing Efficiency: Features a dense molecular matrix that delivers an exceptionally minimal outgassing rate within ultra-high vacuum chambers, preventing process contamination.

Material Constraints & Unsupported Working Environments

  • Vulnerable to Highly Polar Media: FKM compounds are strictly not recommended for exposure to low molecular weight organic acids, volatile ketones (such as acetone, MEK), esters (e.g., ethyl acetate), and nitro compounds, which trigger rapid volumetric swelling and mechanical breakdown. (For total universal chemical resistance, upgrading to FFKM perfluoroelastomer is advised).

  • Vulnerable to High-Pressure Steam: Conventional bisphenol-cured FKM is prone to hydrolytic cleavage in ultra-high temperature water steam environments. For heavy steam routing, specialized peroxide-cured FKM variants or EPDM compounds must be deployed.

Primary Industrial Application Scopes

  • Semiconductor & Optoelectronics Manufacturing: Vacuum chamber door gaskets, Chemical Vapor Deposition (CVD) sub-system gas lines, and high-purity thermal-chemical resistant O-rings.

  • Chemical Processing & Heavy Industrial Pumps: Aggressive chemical media transfer pump seals, chemical-resistant fluid valve seats, and high-temperature autoclave gaskets.

  • Automotive Drivetrain & Aerospace Propulsion: High-pressure fuel injection manifold O-rings, high-RPM crankshaft thermal oil seals, engine valve stem seals, and high-temperature military aviation hydraulic line seals.

Best●   Better○    Good△   BadX

Rubber type
(ASTM Abbreviation )
Fluoro Carbon Rubber
VITON™, FPM, FKM, HK
Chemical structureHexafluoropropylene fluoroethylene copolymer
Main featureHeat-resistant, oil-resistant, chemical-resistant, solvent-resistant; not resistant to ketones, esters and nitrate-containing mixtures.
Pure rubber propertiesproportion
Muni viscosity ML1+ (100℃)
1.80 ∼ 1.82
65 ∼ 180
Physical properties of synthetic rubberPossible JIS hardness range
General temperature range(℃)
Special temperature range(℃)
Tensile strength (kg/cm2)
Elongation (%)
Anti-elastic
Cracking
Wear resistance
Bending resistance
50 ∼ 90
-20 ∼ 200
-30 ∼ 275
70 ∼ 200
500 ∼ 100
△
○
●
○
Various properties of synthetic rubberlubricating oilEngine oil
Gear Oil
Motor oil
Shaft lubricant
Refrigeration oil
Butter
Lithium oil
Oyster sauce
●
●
●
●
●
●
●
●
Working oilPot shaft oil
Oil + Water emulsion system
Water + Glycol
Phosphate ester
Si
Brake Fluid
Gear oil
●
○
○
●
●
△
●
Fuel oilLight oil、kerosene
Heavy oil
Gasoline
●
●
●
WaterWater、Warm water
Water vapor、Hot water
Antifreeze water
Water cutting oil
○
△
○
○
Drug

Hydrochloric acid 20%
Sulfuric acid 30%
Nitric acid 10%
Caustic soda 30%
Benzene
Trichloroethylene
Alcohol
Vinyl glycerol
Liquid fat
Alcohol
Ether
Ketone (MEK)
Acetic acid、Ethyl ester

●
●
●
X
△
△
○
●
○
●
X ~ △
X
X
GasLPG
Urban gas
Ozone
Freon 12
Freon 22
●
●
●
●
△
Other

Food Sanitation Law
Vacuum、Atmosphere 10mm kg 
10-4 ~ 10-9


●
●
The main purposeO ring, diaphragm, box lining, hose, rocket missile, pump parts, etc. Seals for steam, locomotives, diesel engines, and the semiconductor industry.